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Unusual Complex Formation and Chemical Reaction of Haloacetate Anion on the Exterior Surface of Cucurbit[6]uril in the Gas Phase

✍ Scribed by Tae Su Choi, Jae Yoon Ko, Sung Woo Heo, Young Ho Ko, Kimoon Kim, Hugh I. Kim


Book ID
118303466
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
395 KB
Volume
23
Category
Article
ISSN
1044-0305

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Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm