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Unstable 2,2-dibromo-2-ethoxy-4,5-benzo-1,3,2-dioxaphospholane in addition reactions to chloral and benzaldehyde

โœ Scribed by V. F. Mironov; E. N. Ofitserov; I. V. Konovalova; A. N. Pudovik


Book ID
112448799
Publisher
Springer
Year
1991
Tongue
English
Weight
208 KB
Volume
40
Category
Article
ISSN
1573-9171

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The treatment of SH-benzo[f+l,2,3,4+enathiepin ( B'lTP ) or 6H-benzo[g]-l,2,3,4,5-pentathiocin ( BFTC ) with alkenes in the presence of BF3aEt2 afforded trclns adducts, 2,3disubstituted ben~l, (1). which further reacted with alkenes to give cis adducts, 2,3disubstituted benz~l.4ditbiepanes (2).