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Unsaturated, Mixed-Valence Diiron Dithiolate Model for the Hox State of the [FeFe] Hydrogenase

✍ Scribed by Aaron K. Justice; Thomas B. Rauchfuss; Scott R. Wilson

Book ID
101538080
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
133 KB
Volume
119
Category
Article
ISSN
0044-8249

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Unsaturated, Mixed-Valence Diiron Dithio
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31 P NMR (202 MHz, CD 2 Cl 2 ): d = 74.1, 25.0 ppm. IR (CH 2 Cl 2 ): n ˜CO = 2002, 1955 cm À1 ; n ˜NO = 1772 cm À1 . ESI-MS: m/z 762.2 ([Fe 2 -(S 2 C 2 H 4 )(CO) 2 (NO)(PMe 3 )(dppv)] + ). Elemental analysis calcd

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## Abstract A short overview of diiron dichalcogenolato (Se and Te) model complexes related to the chemistry of the diiron subsite of [FeFe] hydrogenase is presented. These model complexes allow direct comparison with the diiron dithiolato compound analogues for their ability to catalyze the format