✦ LIBER ✦
Unresolvable long range spin–spin coupling as a source of systematic error in proton NMR total bandshape analysis
✍ Scribed by Torbjörn Drakenberg; Robert E. Carter
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- English
- Weight
- 218 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
Unresolvable long range spin‐spin coupling which is not explicitly taken into account in total NMR bandshape analysis is demonstrated to be a potentially important source of systematic error, leading to Δ__H__^≠^ and δ__S__^≠^ values incorrect by c. 1 kcal/mol and 2 to 4 cal/(mol K), respectively.