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Unravelling the Mechanism of Force-Induced Ring-Opening of Benzocyclobutenes

✍ Scribed by Jordi Ribas-Arino; Motoyuki Shiga; Dominik Marx


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
425 KB
Volume
15
Category
Article
ISSN
0947-6539

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## Abstract Orbital mapping analysis based on CNDO/2 molecular orbitals has been used to survey the thermal ring‐opening isomerizations of cyclobutenes and benzocyclobutenes. Isoelectronic substitutions within the molecular framework of cyclobutene (e.g., CH~2~ replaced by CH^βˆ’^, OH^+^, NH, NH~2~^+