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Unprecedented Microwave Effects on the Cycloaddition of Fulvenes. A New Approach to the Construction of Polycyclic Ring Systems

✍ Scribed by Hong, Bor-Cherng; Shr, Yeong-Jou; Liao, Ju-Hsiou


Book ID
118269530
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
78 KB
Volume
4
Category
Article
ISSN
1523-7060

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Nitroethylenes bearing either a phenylthio or a phenylselenoether group in b-position are efficient synthetic equivalents of nitroacetylene. A [4+2] cycloaddition/carbenoid-mediated elimination of PhS(e)CH 3 /[4+2] cycloaddition sequence of reactions is shown to produce formal biscycloadducts of nit