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Unperturbed chain dimensions of polyethylene in theta solvents

✍ Scribed by Nakajima, Akio ;Hamada, Fumiyuki ;Hayashi, Seiichi

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
454 KB
Volume
15
Category
Article
ISSN
0449-2994

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Intrinsic viscosity measurements were carried out on dextran samples (of different molecular weights) in aqueous solutions at 25, 28, 31, 34, 37, 40, and 43Β°C. The extrapolation methods were used for the data; they gave unperturbed dimensions, K 0 , of the chain. The unperturbed root-mean-square end

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Intrinsic viscosity measurements were carried out on polystyrene and polyvinylpyridine solutions in various solvents and solvent mixtures. The Stockmayer-Fixman extrapolation was applied to the date: it yields the unperturbed dimensions K s of the chain. A unique value of K e was found for a given p