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Unparalleled, Enormous Metal–Carbon Bond Strength in PdCH2I+

✍ Scribed by Joseph Schwarz; Christoph Heinemann; Detlef Schröder; Helmut Schwarz; Jan Hrušák

Book ID
102255352
Publisher
John Wiley and Sons
Year
1996
Tongue
German
Weight
287 KB
Volume
79
Category
Article
ISSN
0018-019X

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✦ Synopsis

Extensive theoretical studies demonstrate that there is not even an insertion minimum H-Pd'-CH3 on the [Pd,C,H4]' potential-energy surface. See [13].

If not otherwise indicated, all theochemical data are taken from [5].

📜 SIMILAR VOLUMES

Theory-enforced Re-investigation of the
Theory-enforced Re-investigation of the Origin of the Large Metal–Carbon Bond Strength in PdCH2I+ and its reactions with unsaturated hydrocarbons
✍ Joseph Schwarz; Detlef Schröder; Helmut Schwarz; Christoph Heinemann; Jan Hrušák 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 German ⚖ 665 KB

## 2, In [I], a preliminary account of the reaction of ground-state Pd+ with CH,I is given. The experiments were performed in a Spectrospin CMS47X FTICR mass spectrometer in the same manner as reported in [I], and, therefore, we refrain from a further description, except when this is indicated.

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Bond strength of metal–ceramic systems in three-point flexure bond test
✍ Jürgen Lenz; Siegmund Schwarz; Hans Schwickerath; Dr. Franz Sperner; Astrid Schä 📂 Article 📅 1995 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 867 KB

This study deals with a three-point flexure test for the metal-ceramic bond involving geometrically simple specimens (alloy strips partly coated with ceramic) that can be fabricated with reasonable expenditure and sufficient reproducibility. The calculation of the stress distribution in such specime