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Unique syndio-selectivity in CO/styrene copolymerization reaction catalyzed by palladium complexes with 2-(2′-oxazolinyl)-1,10-phenanthrolines

✍ Scribed by Meduri, Angelo; Cozzula, Daniela; D'Amora, Angela; Zangrando, Ennio; Gladiali, Serafino; Milani, Barbara

Book ID
111912228
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
500 KB
Volume
41
Category
Article
ISSN
1477-9226

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✍ Roberto Santi; Anna Maria Romano; Rossella Garrone; Luigi Abbondanza; Mario Scal 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 67 KB

A new class of highly effective homogeneous palladium bis(methoxycarbonyl) complexes Pd(L1L)(COOMe) 2 , where (L1L) are substituted phenanthroline ligands, has been developed for the production of syndiotactic alternating styrene-carbon monoxide copolymers. The essential feature of this novel cataly