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Unique 2:1 Complex with a trans -Chelating Bis-Pyridine Ligand

✍ Scribed by Hu, Yi-Zhen; Chamchoumis, Charles; Grebowicz, Janusz S.; Thummel, Randolph P.


Book ID
126172703
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
74 KB
Volume
41
Category
Article
ISSN
0020-1669

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Polyhydride complexes of rhenium with th
✍ Sandra BolaΓ±o; Jorge Bravo*; Soledad Garcı́a-FontΓ‘n* πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 145 KB

The reaction of [ReOCl 3 (AsPh 3 ) 2 ] with Ph 2 POCH 2 CH 2 OPPh 2 (L) in refluxing THF yielded the complex [ReOCl 3 L] (1). The new polyhydride [ReH 7 L] (2) was obtained by treating 1 with NaBH 4 in absolute ethanol. The heptahydride 2 is stable in the solid state but in solution dimerises, givin