The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO
Unimolecular gas-phase hydrogen randomization within 2-methyl-propane radical cations
β Scribed by Derrick, Peter J.; Falick, A. M.; Burlingame, A. L.
- Book ID
- 127180356
- Publisher
- Royal Society of Chemistry
- Year
- 1975
- Tongue
- English
- Weight
- 458 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
Rate coefficients have been determined for the reaction of butanal and 2-methylpropanal with NO 3 using relative and absolute methods. The relative measurements were accomplished by using a static reactor with long-path FTIR spectroscopy as the analytical tool. The absolute measurements were made us
Dedicated to Professor J. L. Holmes on the occasion of his 60th birthday. The unimolecular chemistry of the methyl carbamate radical cation, H,NCOOCH:\*, 1, has been further investigated by a combination of mass spectrometry-based experiments (mcetastahle ion (MI), collisional activation (CA), coll