Unimolecular dissociation of cyclohexene at extremely high temperatures: behavior of the energy-transfer collision efficiency

Analytical solution of vibrational–rotat

Analytical solution of vibrational–rotational energy transfer in the dissociation and relaxation of N2, Br2, and CO at high temperature

✍ Wendell Forst 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 463 KB

## Abstract An approximate analytical solution of relaxation in a low‐pressure system with exponential transition probabilities is given for vibrational–rotational energy transfer in the dissociation of diatomics. The main assumption is that the rotational degrees of freedom are in thermal equilibr