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Unimolecular and hydrolysis channels for the detachment of water from microsolvated alkaline earth dication (Mg2+, Ca2+, Sr2+, Ba2+) clusters

✍ Scribed by Miliordos, Evangelos; Xantheas, Sotiris S.


Book ID
121511083
Publisher
Springer
Year
2014
Tongue
English
Weight
996 KB
Volume
133
Category
Article
ISSN
1432-2234

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Syntheses, Vibrational Spectroscopy, and
✍ Barbara JΓΌrgens; Elisabeth Irran; Wolfgang Schnick πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 607 KB

The alkaline earth dicyanamides Mg[N(CN) 2 ] 2 , Ca[N(CN) 2 ] 2 , Sr[N(CN) 2 ] 2 , and Ba[N(CN) 2 ] 2 were synthesized by ion exchange using Na[N(CN) 2 ] and the respective nitrates or bromides as starting materials. The crystal structures were determined from X-ray powder di4ractometry: Mg[N(CN) 2