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Unification of the quantum and classical theories of methyl NMR

✍ Scribed by S. Clough

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
80 KB
Volume
14
Category
Article
ISSN
0926-2040

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✦ Synopsis

The existing low and high temperature theories of methyl NMR are not linked because two conditions imposed on state functions in the low temperature theory are not compatible with the classical rotations on which the high temperature theory is based. The conditions do not occur in a geometrical theory of quantum phenomena in which particles and waves have separate roles. When applied to methyl dynamics, this theory covers the whole temperature range.

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