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Ungewöhnlich verbrückte Wolframkomplexe mit W(ER)2 W(ER)3 W-Gerüst (E = S oder Se; R = C2H5, n-C4H9 bzw. C6H5)

✍ Scribed by Luise R. Krauth-Siegel; Luis E. R. Krauth-Siegel; Wolfgang Schulze; Manfred L. Ziegler


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
232 KB
Volume
92
Category
Article
ISSN
0044-8249

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Synthesis and Structure of [Sn4Se11]6–,
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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re