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Unexpected transformation of a diamagnetic Mo3(μ3-S)(μ-S)3 to a paramagnetic Mo3(μ3-S)2(μ-S)3 cluster core by reaction of [Mo3S4(dppe)3Br3]PF6 with tBuSNa

✍ Scribed by Petrov, Pavel A.; Virovets, Alexander V.; Alberola, Antonio; Llusar, Rosa; Konchenko, Sergey N.


Book ID
119950933
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
153 KB
Volume
39
Category
Article
ISSN
1477-9226

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Isolation of a New Cs-Symmetrized Mo3(μ3
✍ Rita Hernandez-Molina; Javier Gonzalez-Platas; Cristian Vicent 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 602 KB

A new cluster of formula {[Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 (dtp) 3 (μ-OAc)][Mo 3 NiS 4 (dtp) 3 (μ-OAc)(CH 3 CN)]} (1; dtp = diethyl dithiophosphate; OAc = acetate) comprising the novel C s -symmetrized Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 structural type covalently attached to a cubane-type Mo 3 NiS 4 core has