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Unexpected stereospecific intramolecular cyclization of 3,3-dimethyl-2,2,4,6,6-pentachloro-5-hexenyl chloride into a cyclobutane derivative

โœ Scribed by S. S. Terzyan; A. R. Mikaelyan; Sh. O. Badanyan


Publisher
SP MAIK Nauka/Interperiodica
Year
1998
Tongue
English
Weight
156 KB
Volume
39
Category
Article
ISSN
0022-4766

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Oxidation of' 3,4-dimethyl-l-phenylphosphole with peracids or peroxides gives a relatively stable P-oxide, which can be used in Diels-Alder reactions to give derivatives with the 7-phosphanorbornene framework. Oxygen insertion into a C-P bond of this framework occurs smoothly with m-chloroperbenzoic