Acid-catalysed benzylidenation reactions of a series of alkyl substituted derivatives of cyclohexane-cis-1,2-diol have been studied. Preferential formation of the exe-phenyl benzyiidene acetal was observed in the initial kinetic phase of the reaction of the 1-tert-butyl derivative, whereas the e~~o-
Unexpected stereoselectivity in the cis dihydroxylation of some 2-cyclopentene-1-carboxamides
β Scribed by Christopher F Palmer; Raymond McCague; Graham Ruecroft; Sean Savage; Stephen J.C Taylor; Christel Ries
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 195 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The title reaction has been studied with 2-methoxypropene, (E)-cyclooctene, ethoxyethene, 1,3-cyclopentadiene, 3methylenecyclohexene, styrene and isoprene as the olefinic substrates. This sequence is one of decreasing reactivity of the substrates towards 2-oxido-2-cyclopenten-1-ylium (1) if [4 + 3]
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