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Unexpected ring contraction and oxidation rearrangement reactions of securinine

✍ Scribed by Jun-Yong Li; Bing-Xin Zhao; Wen Zhang; Chen Li; Xiao-Jun Huang; Ying Wang; Ping-Hua Sun; Wen-Cai Ye; Wei-Min Chen


Book ID
113929415
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
796 KB
Volume
68
Category
Article
ISSN
0040-4020

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## Abstract Reactions of cyclohexanone‐derived enamines (I) with nitrobutene (II) affords cyclic nitronates (III) instead of the expected isomeric nitrones of type (V).