Unexpected Rearrangements of Bicyclic Pyrazolines Derived from 6,6-Diphenylpentafulvene
✍ Scribed by Francis Djapa; Moncef Msaddek; Kabula Ciamala; Joël Vebrel; Claude Riche
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 389 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
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## Abstract 1,3‐Dithianes 1, 1,3‐dithiolanes 2, and diphenyl dithioacetals 3 derived from cinnamaldehydes reacted with 2,3‐dichloro‐5,6‐dicyano‐__p__‐benzoquinone in aqueous solvents to give benzaldehydes 4. Hydride transfer from 1–3 to 2,3‐dichloro‐5,6‐dicyano‐__p__‐benzoquinone followed by hydrol