UNEXPECTED REACTIVITY OF HYPERVALENT ANIONIC SPECIES AS ELECTRON ACCEPTORS
✍ Scribed by Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Gerbier, L.; Reyé, C.
- Book ID
- 120989939
- Publisher
- Taylor and Francis Group
- Year
- 1989
- Tongue
- English
- Weight
- 333 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1042-6507
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Iron(III)‐exchanged sepiolites exhibit dual behaviour as catalysts in the reactions of α‐acetoxystyrenes 1a,b; operating as Lewis acids (to give 2–5) in thermolysis reactions under reduced pressure or as single‐electron acceptors (to give 7) in photolysis under aerobic conditions.
Density functional theory has been used to calculate the thermodynamic properties and molecular orbitals of pillar[n]quinones. Pillar[n]quinones are expected to be effective electron acceptors and the ability to accept more than one electron increases with the size of the interior cavity. Pillar[5]q