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Unexpected reactivity in naphthoquinone series

✍ Scribed by Patrice Vanelle; Thierry Terme; Luc Giraud; Michel P Crozet


Book ID
104211542
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
80 KB
Volume
42
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


An unexpected reactivity of 2-chloromethyl-3-methyl-1,4-naphthoquinone 1 with primary nitroalkanes in classical S RN 1 reaction conditions gives two series of new quinones: dialkyl anthraquinones and C-alkylated naphthoquinones.


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