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Unexpected Reactions of [60]Fullerene Involving Tertiary Amines and Insight into the Reaction Mechanisms

✍ Scribed by Guan-Wu Wang; Xiao-Ping Chen; Xin Cheng


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
187 KB
Volume
12
Category
Article
ISSN
0947-6539

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## Abstract A new PPh~3~‐catalyzed synthesis of alkyl 2‐[aryl(tosylimino)methyl]acrylates from propiolate and __N__‐tosylimine has been developed. Deuterium‐labelling experiments show that the reaction mechanism involves several hydrogen‐transfer processes, which are not the turnover‐limiting step