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Unexpected Participation of an Unconjugated Olefin during Nazarov Cyclization of Bridged Bicyclic Dienones

✍ Scribed by Sören Giese; Robert D. Mazzola Jr.; Clare M. Amann; Atta M. Arif; F. G. West


Book ID
101534268
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
139 KB
Volume
117
Category
Article
ISSN
0044-8249

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✦ Synopsis


The Nazarov reaction is a well-established method for the generation of new cyclopentenone rings from simple dienone precursors. [1] This reaction has enjoyed considerable recent attention with regard to its use in tandem or domino processes, [2] as well as in approaches for controlling the absolute configuration of the stereocenters generated during or after the electrocyclization process. [3] We have recently


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