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Unexpected influence of tetra- and pentafluoroethyl groups on the direction of reactions of 2-polyfluoroalkylchromones with 2-aminoethanol

โœ Scribed by Vyacheslav Ya. Sosnovskikh; Boris I. Usachev


Book ID
119767857
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
151 KB
Volume
10
Category
Article
ISSN
0959-9436

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Arbuzov reactions of diethyl2,2,2-trihaloethyl phosphites (3) with benzoyl chloride afforded ethyl 2,2,2-trihaloethyl benzoylphosphonates (4). The reactions of 4 with NH,OH.HCl led to the formation of methyl benzoate and ethyl methyl H-phosphonate as a result of alcoholysis of 4, followed by alkoxy