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Unexpected formation of the most strained δ-lactone in the pyrolysis of diethyl ester of cis-4-hydroxy-trans-5-methoxy-trans-1,2-cyclohexanedicarboxylic acid

✍ Scribed by V. A. Chertkov; E. K. Dobretsova; D. E. Gremyachinskii; S. S. Golotvin; N. A. Simonov; L. P. Vatlina; V. V. Samoshin

Publisher
Springer US
Year
1997
Tongue
English
Weight
338 KB
Volume
33
Category
Article
ISSN
0009-3122

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## Abstract The irreversible inhibition of __δ__‐chymotrypsin with the enantiomerically pure, P(3)‐axially and P(3)‐equatorially X‐substituted __cis‐__ and __trans‐__configurated 2,4‐dioxa‐3‐phospha(1,5,5‐^2^H~3~)bicyclo[4.4.0]decane 3‐oxides (X=F, 2,4‐dinitrophenoxy) was monitored by ^31^P‐NMR spe