Unexpected formation of ethyl 5-cyano-6-[cyano(4′-phenyl-1,3′-selenazol-2-yl)methyl]-4-(furan-2′-yl)-2-methyl-1,4-dihydropyridine-3-carboxylate
✍ Scribed by V. D. Dyachenko; S. V. Roman
- Book ID
- 111460897
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 130 KB
- Volume
- 81
- Category
- Article
- ISSN
- 1070-3632
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📜 SIMILAR VOLUMES
The title compound, C 18 H 18 N 2 O 5 , was synthesized from 2,3dimethoxyphenylmethylidenemalononitrile and ethyl acetoacetate in the presence of triethylbenzylammonium chloride in an aqueous medium. The pyridone and benzene rings make a dihedral angle of 63.8 (1) . There are intermolecular C-HÁ Á Á
In the title compound, C 17 H 19 N 5 , the almost ideally planar triazole ring forms a dihedral angle of 75.1 (1) with the benzene ring. There are intermolecularinteractions.
In the crystal structure of the title compound, C 16 H 17 N 5 O 2 S, molecules are linked by two N-HÁ Á ÁS hydrogen bonds, with N-S distances of 3.3469 (13) and 3.3703 (13) A ˚and N-H Á Á ÁS angles of 158 and 162 .