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Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene

✍ Scribed by Boris A. Trofimov; Elena Yu. Schmidt; Albina I. Mikhaleva; Nadezhda V. Zorina; Igor A. Ushakov; Andrey V. Afonin; Alexander M. Vasil’tsov


Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
284 KB
Volume
17
Category
Article
ISSN
0959-9436

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The formation of C3H3 (propynyl) radical
✍ Carlos E. Canosa-Mas; Mark Ellis; H. Monty Frey; Robin Walsh 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB

Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase