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Unexpected Formation of 3-Methylsulfanyl-2-phenyl-2-cyclobutenone (VI) in the Reaction of 1,3-Dilithio-2-propynylbenzene (II) with Methoxymethyl Isothiocyanate.

✍ Scribed by O. A. Tarasova; L. Brandsma; N. A. Nedolya; I. A. Ushakov; G. V. Dmitrieva; T. V. Koroteeva


Publisher
John Wiley and Sons
Year
2004
Weight
88 KB
Volume
35
Category
Article
ISSN
0931-7597

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The formation of C3H3 (propynyl) radical
✍ Carlos E. Canosa-Mas; Mark Ellis; H. Monty Frey; Robin Walsh πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 350 KB

Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase