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Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction

✍ Scribed by Alexander M. Vasil’tsov; Alexey B. Zaitsev; Elena Yu. Schmidt; Al’bina I. Mikhaleva; Andrey V. Afonin


Book ID
111730292
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
99 KB
Volume
11
Category
Article
ISSN
0959-9436

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Pyrroles from ketoximes and acetylene. 4
✍ S. E. Korostova; R. N. Nesterenko; A. I. Mikhaleva; S. G. Shevchenko; G. A. Kala 📂 Article 📅 1991 🏛 Springer US 🌐 English ⚖ 439 KB

We have studied the reaction of 1-vinyl-2-(2.furyl). and -(2-thienyl)pyrroles with trifluoroacetic anhydride, with hydrogen in the presence of catalysts (Raney nickel, palladium black, palladous chloride), with propargyl alcohol in electrophUic conditions [catalysis by perfluorobutyric acid in the s