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Unexpected enantioselectivity and activity of penicillin acylase in the resolution of methyl 2,2-dimethyl-1,3-dioxane-4-carboxylate

✍ Scribed by Yiming Yao; Jim J Lalonde


Book ID
114395921
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
62 KB
Volume
22
Category
Article
ISSN
1381-1177

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Enantiomers of 2-methyl- and 2,4-dimethy
✍ Alenka Rutar; UrΕ‘a Ε½bontar; Danijel Kikelj; Ivan Leban πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 260 KB πŸ‘ 1 views

Both enantiomers of 2-methyl-3-oxo-3,4-dihydro-2H-1,4-benzoxazine-2carboxylic acid 2 and 2,4-dimethyl-3-oxo-3,4-dihydro-2H-1,4-benzoxazine-2-carboxylic acid 3 were prepared via resolution of the corresponding racemic carboxylic acids with (R)-and (S)-1-phenylethylamine, respectively. Absolute config