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Unexpected coupling reaction of (F-alkyl)iodides with 1-bromo-1-octyne: access to 1-(F-alkyl)-1-octynes

✍ Scribed by Véronique Sanchez; Jacques Greiner

Book ID
103182533
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
279 KB
Volume
68
Category
Article
ISSN
0022-1139

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A stereoselective route to alkenyl sulfi
A stereoselective route to alkenyl sulfides through the palladium-catalyzed cross-coupling reaction of 9-alkyl-BBN with 1-bromo-1-phenylthioethene or (E)- and (Z)-2-bromo-1-phenylthio-1-alkenes
✍ Yukio Hoshino; Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 247 KB

The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.