𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Unerwartete Reduktion von [Cp*TaCl4(PH2R)] (R = But, Cy, Ad, Ph, 2,4,6-Me3C6H2; Cp* = C5Me5) durch Reaktion mit DBU – Molekülstruktur von [(DBU)H][Cp*TaCl4] (DBU = 1,8-Diazabicyclo[5.4.0]undec-7-en)

✍ Scribed by Steffen Blaurock; Evamarie Hey-Hawkins


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
113 KB
Volume
628
Category
Article
ISSN
0372-7874

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Organometallic Niobium and Tantalum Comp
✍ Steffen Blaurock; Evamarie Hey-Hawkins 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 1 views

The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b