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Unequivocal assignment of the fullerene carbons of diethyl 1,2-methano[60]fullerene 61,61-dicarboxylate using 2D INADEQUATE NMR spectroscopy

✍ Scribed by Glenn A. Burley; Paul A. Keller; Stephen G. Pyne; Graham E. Ball


Book ID
102527042
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
168 KB
Volume
39
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Assignment of all carbons of the [60]fullerene sphere of diethyl 1,2‐methnano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy is described. Acquiring the INADEQUATE data with small spectral widths and optional F~1~ folding with States‐TPPI phase implementation provides a convenient route to high‐resolution data. A description of the topology of the [60]fullerene sphere and its comparison with x‐ray crystallographic analysis is also presented. Copyright © 2001 John Wiley & Sons, Ltd.