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Understanding the thermal [1s,5s] hydrogen shift isomerization of ocimene

✍ Scribed by Eduardo Chamorro,Pablo Ruiz,Jairo Quijano,Diana Luna…


Book ID
126346805
Publisher
Springer-Verlag
Year
2014
Tongue
English
Weight
661 KB
Volume
20
Category
Article
ISSN
1610-2940

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The thermal isomerization of 1,1-dimethy
✍ H. M. Frey; R. K. Solly 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB

The gas phase isomerization of 1,l -dimethyl-2-vinylcyclopropane to cis-2-methylhexa-1,4-diene has been studied in a static system. The isomerization is homogeneous and kinetically first order. The rate constants were independent of initial reactant pressure in the range 0.6 to 2 torr and of added n