Understanding Sterol–Membrane Interactions Part I: Hartree–Fock versus DFT Calculations of 13C and 1H NMR Isotropic Chemical Shifts of Sterols in Solution and Analysis of Hydrogen-Bonding Effects

Understanding Sterol-Membrane Interactio

Understanding Sterol-Membrane Interactions, Part II: Complete 1H and 13C Assignments by Solid-State NMR Spectroscopy and Determination of the Hydrogen-Bonding Partners of Cholesterol in a Lipid Bilayer

✍ Olivier Soubias; Franck Jolibois; Valérie Réat; Alain Milon 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB

## Abstract The complete assignment of cholesterol ^1^H and ^13^C NMR resonances in a lipid bilayer environment (L~α~‐dimyristoylphosphatidylcholine/cholesterol 2:1) has been obtained by a combination of 1D and 2D MAS NMR experiments: ^13^C spectral editing, ge‐HSQC, dipolar HETCOR and J‐based HETC