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Understanding Reactivity at Very Low Temperatures: The Reactions of Oxygen Atoms with Alkenes

✍ Scribed by Sabbah, H.; Biennier, L.; Sims, I. R.; Georgievskii, Y.; Klippenstein, S. J.; Smith, I. W. M.

Book ID
118026921
Publisher
American Association for the Advancement of Science
Year
2007
Tongue
English
Weight
644 KB
Volume
317
Category
Article
ISSN
0036-8075

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On the kinetics of the reactions of oxyg
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The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a