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Undecahalo-closo-undecaborates [B11Hal11]2–

✍ Scribed by O. Volkov; P. Paetzold; C. Hu; U. Kölle

Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
121 KB
Volume
627
Category
Article
ISSN
0372-7874

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Undecaborates M2[B11H11]: Facile Synthes
Undecaborates M2[B11H11]: Facile Synthesis, Crystal Structure, and Reactions
✍ O. Volkov; W. Dirk; U. Englert; P. Paetzold 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 228 KB 👁 1 views

closo-Undecaborates were synthesized by the deprotonation of B 11 H 13 (SMe 2 ) with LitBu in thp or K [BHEt 3 ] in thf, [Li(thp) 3 ] 2 [B 11 H 11 ] and K 2 [B 11 H 11 ] being obtained in 83 and 93% yield, respectively. K 2 [B 11 H 11 ] can be transformed into A 2 [B 11 H 11 ] with the corresponding