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Umsetzung von Perchlor-1,3,5-trisilacyclohexan mit Methylmagnesium-chlorid

✍ Scribed by Prof. Dr. G. Fritz; Dr. N. Szczepanski

Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
212 KB
Volume
79
Category
Article
ISSN
0044-8249

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Reaction of Perchloro-1,3,5-trisilacyclo
Reaction of Perchloro-1,3,5-trisilacyclohexane with Methylmagnesium Chloride
✍ Prof. Dr. G. Fritz; Dr. N. Szczepanski 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB 👁 2 views

of 12 e 1 kcal mole-1 for reaction (1); this value is somewhat smaller than that reported [I], wilhout error limits, for 100 atrn. From the pressure dependence at 23OC, in conjunction with Eq. (2), a volume change, AV, associated with the reaction of 64 f 3 ml/mole is obtained. Both A H and A V decr