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Umpolung of Electrophilic Terminal Phosphinidene Complexes by Interaction with Nucleophilic Carbenes

✍ Scribed by Ngoc Hoa Tran Huy; Bruno Donnadieu; Guy Bertrand; François Mathey


Book ID
112005770
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
195 KB
Volume
4
Category
Article
ISSN
1861-4728

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Electrophilic Terminal-Phosphinidene Com
✍ François Mathey; Ngoc Hoa Tran Huy; Angela Marinetti 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 252 KB 👁 1 views

In memory of Professor Luigi M. Venanzi, a highly respected inorganic chemist Electrophilic and nucleophilic terminal-phosphinidene complexes are compared in terms of electronic structures and reactivities. Various precursors of the unstable electrophilic species [RÀPÀM] (M Cr, Mo, W(CO) 5 and Fe(CO