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Umlagerungen von Derivaten des Benzo[b]-thiepins und Benzo[b]thiepin-1,1-dioxids

✍ Scribed by Priv.-Doz. Dr. H. Hofmann; Dipl.-Chem. H. Westernacher


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
121 KB
Volume
79
Category
Article
ISSN
0044-8249

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Rearrangements of Derivatives of Benzo[b
✍ Priv.-Doz. Dr. H. Hofmann; Dipl.-Chem. H. Westernacher πŸ“‚ Article πŸ“… 1967 πŸ› John Wiley and Sons 🌐 English βš– 227 KB

Whereas free BN radicals with unresolved ESR signals are formed on dehalogenation of pyridine-and 2-alkylpyridinedialkylchloroboranes by lithium in tetrahydrofuran 111 at 0 to 5"C, associated radicals ( I ) , whose ESR spectra show a hyperfine structure of ten lines (distances: 3.83 gauss), are obta