✦ LIBER ✦
Ultraviolet spectroscopy of benzene in cyclohexane clusters. Further evidence for structural shells and resonance interactions
✍ Scribed by M.Samy El-Shall; Robert L. Whetten
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 621 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Spectral lineshapes of benzene/cyclohexane clusters (BC,=+ ,, N=2-20) have been obtained by resonant two-photon ionization spectroscopy in the vicinity of the benzene A ig+Bzu 61, transition. An analysis of spectral shifts and multiplicities provides support for the structural shell-filling model used previously to account for (benzene)Ncluster spectra. In particular, evidence for isomeric forms of the BC6 cluster is interpreted in terms of axial and equatorial sites in the pentagonal bipyramid structure.