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Ultraviolet absorption and cross sections of propargyl (C3H3) radicals in the 230–300 nm region

✍ Scribed by Askar Fahr; Parviz Hassanzadeh; Barna Laszlo; Robert E. Huie

Book ID
108430551
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
563 KB
Volume
215
Category
Article
ISSN
0301-0104

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Influence of the radical size on the Ca∗ + ROH → CaOH∗ + R (RCH3, C2H5 and C3H7) reaction cross section
✍ M. Esteban; M. Garay; J.M. García-Tijero; E. Verdasco; A.González Ureña 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 430 KB

Absolute values of the reaction cross section, CT,, for the title reaction family have been measured by chemiluminescence emission under beam-gas conditions. The uR values diminish as the radical group R increases in size, showing an important overall steric effect. These results are discussed in th