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Ultrasound-induced electrochemical synthesis of the anions selenide (Se22-, Se2-), and telluride (Te22-, and Te2-)

✍ Scribed by Gautheron, Bernard; Tainturier, Gerard; Degrand, Chantal


Book ID
127106593
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
402 KB
Volume
107
Category
Article
ISSN
0002-7863

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Tl 2 Ch 22- (Ch = Se and/or Te) Anions:
NiIV cubanes: synthesis and characteriza
✍ Jonathan M. McConnachie; Mohammad A. Ansari; James A. Ibers πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 1013 KB

The compounds [NEt,],[Ni$e,(Se,),(Se,)] axNEt& (x= 0, 1) and [NEt&[Ni.,Te4(Te2)2(Te3)41 have been prepared from the reaction in DMF of Ni(S2COEt)2 with L&Se and Se or Li,Te and Te, respectively. These compounds result from spontaneous assembly reactions in which Nix1 centers are oxidized to Niw with