Ultrasonically initiated emulsifier-free emulsion copolymerization of n-butyl acrylate and acrylamide. Part I: Polymerization mechanism
β Scribed by Nianwei Yin; Keqiang Chen
- Book ID
- 108247767
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 266 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
The photolysis of n-butyl-(N,N-diethyl dithiocarbamyl)propionate (RTC), an initiator for "livingΓ free radical polymerizations, has been investigated in order to elucidate the mechanism of these polymerizations. The photolysis yields tetraethylthiuram disulphide (TED), and its degradation products,
The polymerization of n-butyl acrylate (BuAc) initiated with a model compound (butyl-2-(N,N-diethyldithiocarbamyl)propionate, RTC) has been investigated. The living character of this polymerization has been assessed and compared with those of styrene and methyl methacrylate. The small variation of w
Emulsifier-free emulsion polymerization of n-butyl acrylate has been performed in the presence of a polymerizable sulfobetaine monomer, 1,1-(dimethyl)-1-(3methacryloxyethyl)-1-(sulfopropyl)ammonium betaine (SPE). An investigation of the effect of various salts (NaCl, NaHCO 3 , Na 2 CO 3 , and NaH 2