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Ultrasonic relaxation and the volume difference between the rotational isomers in 1,2-dichloroethane

✍ Scribed by W. Seki; P.-K. Choi; K. Takagi

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
336 KB
Volume
98
Category
Article
ISSN
0009-2614

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✦ Synopsis

Spectra of ultrasonic velocity and absorption

observed in 1 ,Zdichloroerhane revealed relaxation around 1.5 GHz due fo rotJtiona1 isomerism _ Andy sis of the spectra showed the important role of the volume difference between the isomers which u's estimated to be 7% with the knowledge of AH = 0.0 kcal/mol obtained by infrared experiments.

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