## Abstract Various segmented polyurethanes with a hard segment content of about 50 wt% were prepared from 4,4β²βdiphenylmethane diisocyanate (MDI), a poly(tetramethylene adipate) glycol with an __M__~n~ of 2000, and various combinations of aliphatic diols as chain extenders by a oneβshot, handβcast
Ultrasonic detection of segmental relaxations in thermoplastic polyurethanes
β Scribed by A. W. Aziz; S. N. Lawandy
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 402 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The change in attenuation of longitudinal waves has been measured as a function of frequency and temperature for thermoplastic polyurethanes of different hardness covering a range from rubbery hardness to plastic. Analysis of the results show some segmental relaxations and the activation energies were calculated from the ultrasonic measurements. These activation energies were indirectly related to the fatigue failure of the polymer. This failure was expressed as cut growth.
π SIMILAR VOLUMES
The yield stress of polyacetal (POM) decreases monotonically with the incorporation of thermoplastic polyurethane (TPU) elastomer in POM/TPU blends as would be anticipated. However, the impact strength of the resultant POM/TPU blends increases initially up to 30% TPU and thereafter decreases with th
Thermoplastic polyurethane elastomers were prepared from 4,4-diphenylmethane diisocyanate (MDI)/1,4-butanediol (BD)/poly(propylene glycol) (PPG) and MDI/BD/poly(oxytetramethylene glycol) (PTMG). The MDI/BD-based hard-segment content of polyurethane prepared in this study was of 39 -65 wt %. These po
Stress relaxation behavior of short Kevlar fiber-reinforced thermoplastic polyurethane ( T P U ) is studied with respect to strain level, strain rate, fiber loading, and fiber orientation and temperature. The existence of a two-step relaxation mechanism for unfilled stock and a three-stage relaxatio