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Ultrasonic Absorption Spectra in Aqueous Solutions of Alkylamines. Effect of Isotopic Solvents on Kinetics of Hydrolysis and Aggregation Reactions

✍ Scribed by Huang, Hua; Nishikawa, Sadakatsu

Book ID: 126845025
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 80 KB
Volume: 104
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp994062r

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## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^−1^, Bu~4~N^+^ is the cation) and as “free” (solvated) ion in DMF. The add