Ultraproductive, Zinc-Mediated, Immortal Ring-Opening Polymerization of Trimethylene Carbonate
✍ Scribed by Marion Helou; Olivier Miserque; Jean-Michel Brusson; Jean-François Carpentier; Sophie M. Guillaume
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 256 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The biomedical applications of poly(ε‐caprolactone) (PCL) were limited for its high hydrophobicity and crystallinity. In this study, we copolymerized CL with amorphous 5‐hydroxyl‐trimethylene carbonate (HTMC) to solve the problem. The 5‐benzyloxy‐trimethylene carbonate (BTMC) was synthe
The zinc alkoxide complex prepared in situ from the reaction of (BDI)Zn(N(SiMe 3 ) 2 ) is an efficient catalyst for both the solution and bulk ring-opening polymerization (ROP) of racemic-bbutyrolactone (BBL). The controlled ''immortal'' ROP of BBL using the binary catalytic system (BDI)Zn(N(SiMe 3