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Ultrahigh Resolution Isotope Distribution Calculations

โœ Scribed by Alan L. Rockwood; Steven L. Van Orden; Richard D. Smith


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
653 KB
Volume
10
Category
Article
ISSN
0951-4198

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โœฆ Synopsis


A modification of a previously described Fourier-transform-based algorithm for calculating isotope distributions is presented. It allows one to calculate ultrahigh resolution isotope distributions on computers having limited memory resources and incudes a peak-shape function as an inherent part of the calculation. The method zoomsin on a limited mass range and uses digital filtering to reduce the required array size for the calculation. Alternative methods typidy have very unfavorable scaling properties as molecular weight increases, making them unsuitable for this application. At present, the method is probably the only practicable way to calculate ultrahigh resolution isotope distributions of very large resources.


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Separation of isotopically labeled [ 14 N]/[ 15 N] ammonium was performed with capillary electrophoresis. This ultrahigh-resolution separation was based on mobility counterbalance with precise control of the anodic electroosmotic flow. Mixtures of zwitterionic surfactant (Rewoteric AM CAS U) and cat